Green Chemistry · 2016 · 172 citations · 51 references
Natural SciencesChemical EngineeringChemistryCatalysisGreen ChemistryReaction EngineeringBiomass ConversionCatalyst PreparationCatalytic MechanismsCatalytic Reaction EngineeringIndustrial CatalysisIndustrial Catalytic ProcessesAromatic HydrocarbonsBiomass Conversion CatalysisBiomass HydrolysisBiomass ValorizationCatalytic Biomass ConversionLignin-derived Compounds
In the context of arenes generated from bioresources, a hydrothermally stable catalyst Ru/HZSM-5 is reported for the quantitative conversion of lignin-derived phenol, anisole, guaiacols, and syringols into bioaromatic hydrocarbons in a one-pot aqueous-phase process in moderate conditions (240 °C, 2 bar H<sub>2</sub>), with a high carbon balance of 98.6%.
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Formic-acid-induced depolymerization of oxidized lignin to aromatics
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