Effect of Al Speciation on the Structure of High‐Al Steels Mold Fluxes Containing Fluoride

Abstract

To design suitable mold fluxes for the casting of high‐Al steels, the structure of mold fluxes based on CaO–SiO 2 , CaO–SiO 2 –Al 2 O 3 , and CaO–Al 2 O 3 was examined by Raman spectroscopy and magic‐angle spinning nuclear magnetic resonance. The results showed that Si atoms are replaced by Al atoms as the network formers with the increase in Al 2 O 3 in the mold fluxes. This converts the silicate slags (CaO–SiO 2 mold fluxes) into aluminosilicates slags (CaO–SiO 2 –Al 2 O 3 or CaO–Al 2 O 3 mold fluxes). The F − ions in the mold flux containing Al 2 O 3 are classified into three categories, according to function: Bridging F's, Nonbridging F's, and Free‐F's. The Al 3+ ion holds three distinct coordination environments: IV Al, V Al, and VI Al. The addition of F affects the coordination environment of Al 3+ to form AlO 3 F and AlO 2 F 2 that accommodate the network structure of slags. The network structure in the CaO–SiO 2 mold fluxes is mainly connected through Si–O–Si linkage. However, the network structure of the mold fluxes containing elevated content of Al 2 O 3 is mainly connected through Si–O–Si, Al–O–Al, Al–O–Si, and Al–F–Al linkages. Hence, the structural characteristics of high‐Al steels mold fluxes must be considered during the designing step of the mold fluxes.