Publication | Closed Access
Aluminum Monohydride Catalyzed Selective Hydroboration of Carbonyl Compounds
174
Citations
41
References
2016
Year
Carbonyl CompoundsChemical EngineeringEngineeringDisplayed Chemoselective HydroborationOrganic ChemistryOrganometallic CatalysisCatalysisChemistryHeterocycle ChemistryWide RangeCatalytic SynthesisMild Reaction Conditions
The well-defined aluminum monohydride compound [{(2,4,6-Me3-C6H2)NC(Me)}2(Me)(H)]AlH·(NMe2Et) (1) catalyzes hydroboration of a wide range of aldehydes and ketones under mild reaction conditions. Moreover, compound 1 displayed chemoselective hydroboration of aldehydes over ketones at rt.
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