Azomesogens containing an ethoxyethyl terminal chain: synthesis and characterization

Abstract

Abstract Two homologous mesogenic series, the ethoxyethyl 4-(4′-n-alkoxyphenylazo)benzoates (I) and the ethoxyethyl [4-(4′-n-alkoxybenzoyloxy)phenylazo]-4″-benzoates (II), both containing a terminal ethoxyethyl chain, have been synthesized. In series I, all nine members synthesized exhibit only an enantiotropic smectic A mesophase. In series II, all 12 homologues exhibit an enantiotropic nematic mesophase; a smectic A phase appears in the n-butyloxy derivative as a enantiotropic phase and persists through to the n-hexadecyloxy member. The mesomorphic properties of both series are compared with each other and also with the properties of other structurally related series to evaluate the effects of the ethoxyethyl chain on mesomorphism. Notes †This paper was presented at the 8th National Conference on Liquid Crystals held at Department of Physics, Mumbai University, Mumbai, India, December 28–30, 2002.