Synchrotron-Based Highest Resolution Terahertz Spectroscopy of the ν₂₄ Band System of 1,2-Dithiine (C₄H₄S₂): A Candidate for Measuring the Parity Violating Energy Difference between Enantiomers of Chiral Molecules

Abstract

The chiral C₂ symmetric molecule 1,2-dithiine (1,2-dithia-3,5-hexadiene, C₄H₄S₂) has been identified as a possible candidate for measuring the parity violating energy difference between enantiomers. We report here the observation and analysis of the low-frequency fundamental ν₂₄ using highest resolution synchrotron-based interferometric Fourier transform infrared (FTIR) spectroscopy in the terahertz range with a band center of ν₀ = 6.95375559 THz (ν̃₀ = 231.952319 (10) cm^-1) and two related hot bands, the (ν₁₃ + ν₂₄) ← ν₁₃ band at ν₀ = 6.97256882 THz (ν̃₀ = 232.579861 (33) cm^-1) and the 2ν₂₄ ← ν₂₄ band at ν₀ = 7.01400434 THz (ν̃₀ = 233.962001 (14) cm^-1). This success in the difficult analyses of the THz spectrum of a complex chiral molecule of importance for fundamental tests on molecular parity violation is enabled by the ideal setup of an FTIR experiment of currently unique resolution with the very stable and bright synchrotron radiation at the Swiss Light Source (SLS).