Reliability of Small Molecule Organic Photovoltaics with Electron‐Filtering Compound Buffer Layers

Abstract

Electron‐filtering compound buffer layers (EF‐CBLs) improve charge extraction in organic photovoltaic cells (OPVs) by blending an electron‐conducting fullerene with a wide energy gap exciton‐blocking molecule. It is found that devices with EF‐CBLs with high glass transition temperatures and a low crystallization rate produce highly stable morphologies and devices. The most stable OPVs employ 1:1 2,2′,2″‐(1,3,5‐benzenetriyl tris ‐[1‐phenyl‐1 H ‐benzimidazole] TPBi:C 70 buffers that lose <20% of their initial power conversion efficiency of 6.6 ± 0.6% after 2700 h under continuous simulated AM1.5G illumination, and show no significant degradation after 100 days of outdoor aging. When exposed to 100‐sun (100 kW m −2 ) concentrated solar illumination for 5 h, their power conversion efficiencies decrease by <8%. Moreover, it is found that the reliability of the devices employing stable EF‐CBLs has either reduced or no dependence on operating temperature up to 130 °C compared with BPhen:C 60 devices whose fill factors show thermally activated degradation. The robustness of TPBi:C 70 devices under extreme aging conditions including outdoor exposure, high temperature, and concentrated illumination is promising for the future of OPV as a stable solar cell technology.