BiFSeO₃: An Excellent SHG Material Designed by Aliovalent Substitution

Abstract

The first bismuth selenite fluoride, BiFSeO3, was obtained by aliovalent substitution of 2D BiOIO3. Its structure features a 3D network composed of 1D [BiF](2+) chains interconnected by SeO3 groups. BiFSeO3 exhibits a very strong second harmonic generation (SHG) effect of about 13.5 times that of KH2PO4 (KDP) under 1064 nm laser radiation and 1.1 times that of KTiOPO4 (KTP) under 2.05 μm laser radiation, which is the highest among all of the metal selenites reported. It has also very simple chemical composition and can be synthesized easily under mild hydrothermal conditions.