Publication | Closed Access
Polymerization by Carbenoids, Carbenes, and Nitrenes
44
Citations
33
References
1972
Year
EngineeringOrganic ChemistryAbstract CarbenesChemistryHeterocycle ChemistryTriplet StateChemical EngineeringOrganometallic CatalysisPolymer ChemistryMaterials ScienceDivalent CarbonsCatalysisSynthesis MethodHeterocyclicAlkene MetathesisPolymer SciencePolymerization KineticsPolymer ReactionPolymer Synthesis
Abstract Carbenes are divalent carbons, as shown by :CR2, and have two electron spin states distinguished by a singlet state (S) and a triplet state (T). One of the best methods to generate a carbene is through the decomposition of a diazo compound by irradiation or by heating, especially in the presence of a solvent or of a catalyst:
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