Publication | Closed Access
New Entry to γ,δ-Unsaturated Seven-membered Lactones
14
Citations
2
References
1990
Year
Crystal StructureCatalytic Rhodium AcetateDerivativesDiazo MalonatesBiochemistryEngineeringNatural SciencesOrganic Chemistryδ-Unsaturated Seven-membered LactonesCatalysisMain Group ChemistryChemistrySynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringGood Yields
Abstract The [2,3]sigmatropic rearrangement of cyclic allyl sulfonium ylides, generated from the diazo malonates of 2-phenylthio-3-butenol derivatives with catalytic rhodium acetate, afforded γ,δ-unsaturated seven-membered lactones in moderate to good yields.
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