Journal of Microwave Power and Electromagnetic Energy · 1995 · 53 citations · 13 references
Natural SciencesChemical EngineeringChemistryChemical KineticsMicrowave EngineeringOrganic ChemistryOrganic SynthesisRadical ReactionsMicrowave Heating MechanismsMicrowave-specific Reaction EffectsOrganic Compound ReactionsOrganic Reaction MechanismsReaction Kinetics Under Microwave IrradiationTemperature Dependence Of Reaction RatesTemperature-dependent Reaction KineticsTemperature-dependent Reaction Rate
Four different organic reactions, where specific aciivation by microwaves has been suggested, have been inve vtigated. In each case, the claim that microwave radiation activates organic molecules and leads to increased reaction rates has been shown to be unfounded. All the increased rates of reaction in the microwave oven reactions can be attributed to the increased reaction temperature.
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The use of microwave ovens for rapid organic synthesis
Richard Gedye, Frank E. Smith, Kenneth Charles Westaway et al. · Tetrahedron Letters · 1986 · 1.7K citations
Application of commercial microwave ovens to organic synthesis.
R. J. GIGUERE, Terry Bray, Scott M. Duncan et al. · Tetrahedron Letters · 1986 · 1.1K citations