New function of the Yb3+ ion as an efficient emitter of persistent luminescence in the short-wave infrared

Abstract

The trivalent ytterbium (Yb³⁺) ion has been extensively used as an emitter in short-wave infrared (SWIR) lasers, a sensitizer to activate other lanthanide ions for up-conversion luminescence, and a spectral converter in Ln³⁺-Yb³⁺ doubly doped quantum cutting phosphors. Here we report a new function of the Yb³⁺ ion-as an efficient emitting center for SWIR persistent luminescence. We have developed the first real SWIR persistent phosphor, MgGeO₃:Yb³⁺, which exhibits very-long persistent luminescence at around 1000 nm for longer than 100 h. The MgGeO₃:Yb³⁺ phosphor is spectrally transparent to visible/near-infrared light (~400-900 nm) and is a promising ultraviolet-to-SWIR spectral convertor. The MgGeO₃:Yb³⁺ phosphor also exhibits a photostimulated persistent luminescence capability, where the SWIR persistent emission in an ultraviolet-light pre-irradiated sample can be rejuvenated by low-energy light (white or red light) stimulation. The MgGeO₃:Yb³⁺ phosphor is expected to have promising applications in biomedical imaging, night-vision surveillance and photovoltaics.