Chemical Communications · 2016 · 30 citations · 36 references
Natural SciencesBiochemistryChemistryPolymer ChemistryPolymer MaterialsSupramolecular ChemistryConformational ChangeMacromolecular StructurePolymer ConformationSelf-assemblySupramolecular MaterialsSupramolecular PolymersChiral Self-assemblyChiral Supramolecular MaterialsFlexibilityMolecular Conformation ControlMolecular Conformation In SolutionOrganic Self-assemblyPolymer Molecular ConformationSupramolecular Self-assembly
We report the synthesis and self-assembly of chiral, conformationally flexible C3-symmetrical trisamides. A strong Cotton effect is observed for the supramolecular polymers in linear alkanes but not in cyclic alkanes. MD simulations suggest 2 : 1 conformations of the amides within the aggregates in both types of solvents, but a chiral bias in only linear alkanes.
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