Rational synthesis of a novel 3,3,5-c polyhedral metal–organic framework with high thermal stability and hydrogen storage capability

Abstract

By using a functionalized ligand strategy, an uncommon (3,3,5)-c polyhedron-based metal–organic framework named <bold>GDMU-2</bold> has been constructed, which has a high H₂ uptake of 240.7 cm³ g⁻¹ (2.16 wt%) at 77 K and 1 bar.