Concepedia

Reactivity of (poly)fluorobenzamides in palladium-catalysed direct arylations

Nouria Laidaoui, Mian He, Douniazad El Abed, Jean‐François Soulé, Henri Doucet

RSC Advances · 2016 · 11 citations · 54 references

DOI

Concepts

Abstract

Under PdCl<sub>2</sub>/PivOK as reaction conditions, fluoro substituents act as better directing groups than amides in the palladium-catalysed direct arylations.

References

54

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

Joanna Wencel‐Delord, Frank Glorius · Nature Chemistry · 2013 · 2.3K citations

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Beyond Directing Groups: Transition‐Metal‐Catalyzed CH Activation of Simple Arenes

Nadine Kuhl, Matthew N. Hopkinson, Joanna Wencel‐Delord et al. · Angewandte Chemie International Edition · 2012 · 1.6K citations

Catalytic Intermolecular Direct Arylation of Perfluorobenzenes

Marc Lafrance, Christopher N. Rowley, Tom K. Woo et al. · Journal of the American Chemical Society · 2006 · 839 citations

, , +9

Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation

Chang‐Liang Sun, Bi‐Jie Li, Zhang‐Jie Shi · Chemical Communications · 2010 · 775 citations

Catalytic Direct Arylation of Heteroaromatic Compounds

Tetsuya Satoh, Masahiro Miura · Chemistry Letters · 2006 · 676 citations

, , +14