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Reversible phase transition driven by order–disorder transformations of metal-halide moieties in [(C<sub>6</sub>H<sub>14</sub>)NH<sub>2</sub>]<sub>2</sub>·CuBr<sub>4</sub>
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Citations
25
References
2016
Year
Materials ScienceInorganic ChemistryOrganic–inorganic Hybrid MaterialMolecular SolidEngineeringTransition Metal ChalcogenidesPhysicsMetal-halide MoietiesMetal-coordinated Halogen AtomsOrder–disorder TransformationNatural SciencesCondensed Matter PhysicsApplied PhysicsTheoretical Inorganic ChemistryChemistryReversible Phase TransitionCrystallographyOrder–disorder Transformations
[(C<sub>6</sub>H<sub>14</sub>)NH<sub>2</sub>]<sub>2</sub>·CuBr<sub>4</sub> (<bold>1</bold>), an organic–inorganic hybrid material, undergoes a reversible first-order phase transition around 194 K, triggered by the order–disorder transformation of metal-coordinated halogen atoms.
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