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TEMPO-tert-Butyl Nitrite: An Efficient Catalytic System for Aerobic Oxidation of Alcohols
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Citations
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References
2009
Year
Oxygen Reduction ReactionChemical EngineeringCatalytic ApplicationEngineeringMetal-free Catalytic SystemNon-active AlcoholsMolecular OxygenCatalytic SynthesisOrganic ChemistryCatalysisMolecular CatalysisChemistryAerobic OxidationCatalytic ProcessTempo-tert-butyl NitriteEfficient Catalytic System
A metal-free catalytic system consisting of 2,2,6,6-tetramethylpiperidine N-oxyl (TEMPO) and tert-butyl nitrite has been developed to activate molecular oxygen for the aerobic oxidation of alcohols. A variety of active and non-active alcohols were oxidized to their corresponding carbonyl compounds in high selectivity and yields.
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