Photochemical reduction of carbon dioxide coupled with water oxidation using various soft-oxometalate (SOM) based catalytic systems

Santu Das, Subharanjan Biswas, Tuniki Balaraju, Soumitra Barman, Ramudu Pochamoni, Soumyajit Roy

Journal of Materials Chemistry A · 2016 · 47 citations · 54 references

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Abstract

We report soft-oxometalate catalytic systems based on various metal oxide catalysts to oxidize H<sub>2</sub>O and utilize the generated H<sup>+</sup>s and e<sup>−</sup>s for reduction of CO<sub>2</sub> with a TON of 1366 (effectively 1.4 x 10<sup>6</sup>).

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54