ChemSusChem · 2016 · 114 citations · 17 references
Natural SciencesChemical EngineeringChemistryCatalysisInorganic ChemistryReaction EngineeringCatalyst PreparationCatalyst SynthesisCatalytic MaterialsCatalytic MechanismsRedox CatalysisSupported CatalystsCatalyst MechanismsCatalyst Structure - Activity RelationshipsIron CatalysisIron-catalyzed OxidationMetal Oxide Catalyst SynthesisMetal Oxide CatalystsMetal-catalyzed OxidationMethane
The presence of a Fe-FeAl2 O4 structure over an Fe-Al2 O3 catalysts is demonstrated to be vital for the catalytic methane decomposition (CMD) activity. After H2 reduction at 750 °C, Fe-Al2 O3 prepared by means of a fusion method, containing 86.5 wt % FeAl2 O4 and 13.5 wt % Fe(0) , showed a stable CMD activity at 750 °C for as long as 10 h.
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Kinetics of reduction of iron oxides by H2
A. Pineau, Ndue Kanari, I. Gaballah · Thermochimica Acta · 2005 · 530 citations
Reduction of Fe2O3 with hydrogen
Jerzy Zieliński, Ilona Zglinicka, Leszek Znak et al. · Applied Catalysis A General · 2010 · 424 citations