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Ag<sub>2</sub>CO<sub>3</sub>/CA-AA-AmidPhos Multifunctional Catalysis in the Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylides
38
Citations
48
References
2016
Year
Asymmetric CatalysisInorganic ChemistryChemical EngineeringEnantioselective SynthesisEngineeringAzomethine YlidesOptimal ConditionsOrganic ChemistryOrganometallic CatalysisCatalysisChemistryNew Ag2co3/ca-aa-amidphos ComplexesEnantioselective 1,3-Dipolar CycloadditionSynthetic ChemistryAsymmetric 1,3-Dipolar CycloadditionBiomolecular Engineering
The new Ag2CO3/CA-AA-amidphos complexes have been demonstrated as highly efficient multifunctional catalysts in the asymmetric 1,3-dipolar cycloaddition of azomethine ylides. Under optimal conditions, highly functionalized endo-4 pyrrolidines were obtained with excellent yields (up to 99% yield) and enantioselectivities (up to 96% ee).
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