Science · 2016 · 329 citations · 48 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsMagnetic MaterialsSurface ScienceFerromagnetic MaterialsMagnetic OxidesMagnetic Properties Of SolidsMagnetism In SolidsPermanent MagnetsSurface MagnetismMagnetic RemanenceMagnetization DynamicsMagnetization ReversalMolecular MagnetismSpin RelaxationSpin Relaxation Mechanisms
Metal atoms adsorbed on surfaces can develop strong magnetization in an applied field, a phenomenon explored in molecular magnetism. The study aims to create a permanent magnet from a single atom. The atom avoids spin relaxation through quantum‑state symmetry and the oxide film blocking tunneling to the metal substrate. Single holmium atoms on MgO/Ag exhibit residual magnetism up to 30 K and bistability lasting 1500 s at 10 K. Published in Science, issue p.
Stable magnets from single atoms An important goal in molecular magnetism is to create a permanent magnet from a single atom. Metal atoms adsorbed on surfaces can develop strong magnetization in an applied field (paramagnetism). Donati et al. show that single holmium atoms adsorbed on a magnesium oxide film grown on a silver substrate show residual magnetism for temperatures up to 30 K and bistabilty that lasts for 1500 s at 10 K (see the Perspective by Khajetoorians and Heinrich). The atom avoids spin relaxation by a combination of quantum-state symmetry and by the oxide film preventing the spin from interacting with the underlying metal via tunneling. Science , this issue p. 318 ; see also p. 296
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Generalized Gradient Approximation Made Simple
John P. Perdew, Kieron Burke, Matthias Ernzerhof · Physical Review Letters · 1996 · 211.5K citations · Full text
Natural Sciences, Chemistry, Physics +16