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A facile and chemoselective conjugate reduction using polymethylhydrosiloxane (PMHS) and catalytic B(C6F5)3
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Citations
60
References
2006
Year
Asymmetric CatalysisChemical EngineeringEngineeringBiochemistryNatural SciencesOrganic ChemistryOrganometallic CatalysisCatalysisSynthetic ChemistryChemistryCatalytic BChemoselective Conjugate ReductionElectron-deficient Michael AcceptorsEnantioselective SynthesisCatalytic Synthesis
A highly chemoselective conjugate reduction of electron-deficient Michael acceptors, including alpha,beta-unsaturated ketones, carboxylic esters, nitriles and nitro compounds with PMHS in the presence of catalytic B(C6F5)3 is described.
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