Asymmetric Synthesis of Planar Chiral Ferrocenes by Enantioselective Intramolecular C–H Arylation of <i>N</i>-(2-Haloaryl)ferrocenecarboxamides - Concepedia

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Asymmetric Synthesis of Planar Chiral Ferrocenes by Enantioselective Intramolecular C–H Arylation of <i>N</i>-(2-Haloaryl)ferrocenecarboxamides

119

Citations

45

References

2014

Year

Lantao Liu, An‐An Zhang, Ruijuan Zhao, Feng Li, Tuanjie Meng, Naoki Ishida, Masahiro Murakami, Wen‐Xian Zhao

Organic Letters

Abstract

The palladium-catalyzed intramolecular C-H arylation reaction of N-(2-bromoaryl)ferrocenecarboxamides furnishes planar chiral ferrocene derivatives. TADDOL-derived phosphoramide ligands induce enantioselectivities ranging from 91:9 to 98:2 er.

References

	Year	Citations

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