Effects of Inorganic and Organic Salts on Aggregation Behavior of Cationic Gemini Surfactants

Abstract

All salts studied effectively reduce critical micelle concentration (CMC) values of the cationic gemini surfactants. The ability to promote the surfactant aggregation decreases in the order of C(6)H(5)COONa > p-C(6)H(4)(COONa)(2) > Na(2)SO(4)> NaCl. Moreover, only C(6)H(5)COONa distinctly reduces both the CMC values and the surface tension at CMC. For 12-4-12 solution, the penetration of C(6)H(5)COO(-) anions and charge neutralization induce a morphology change from micelles to vesicles, whereas the other salts only slightly increase the sizes of micelles. The 12-4(OH)(2)-12 solution changes from the micelle/vesicle coexistence to vesicles with the addition of C(6)H(5)COONa, whereas the other salts transfer the 12-4(OH)(2)-12 solution from the micelle/vesicle coexistence to micelles. As compared with 12-4-12, the two hydroxyls in the spacer of 12-4(OH)(2)-12 promote the micellization of 12-4(OH)(2)-12 and reduce the amounts of C(6)H(5)COONa required to induce the micelle-to-vesicle transition.