Australian Journal of Chemistry · 1955 · 42 citations · 0 references
Second Virial CoefficientsEngineeringPhysicsPhase EquilibriumNatural SciencesGas DynamicNumerical SimulationMixtures Ch4-cPhysical ChemistryCoefficients B12Experimental ThermodynamicsThermodynamicsChemistryQuantum ChemistryEquilibrium Thermodynamic PropertySeveral TemperaturesSolution (Chemistry)
The second virial coefficients of the mixtures CH4-C(CH3)4, CH4-Si(CH3)4, and CH4-SF6 have been measured for several compositions and at several temperatures. Values of the coefficients B12, derived from the results, fail to conform to Guggenheim and McGlashan's (1951) extension of the principle of corresponding states. Reasons are given for this disagreement.