Publication | Closed Access
Direct Observation of a {Re<sub>6</sub>(μ<sub>3</sub>-S)<sub>8</sub>} Core-to-Ligand Charge-Transfer Excited State in an Octahedral Hexarhenium Complex
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Citations
34
References
2011
Year
Inorganic ChemistryElectronic Excited StateExcited State PropertyEngineeringPhotochemistryNatural SciencesCoordination ComplexDirect ObservationCore-to-ligand Charge-transfer CharacterMolecular ComplexQuantum ChemistryChemistryNew ComplexTransient Absorption SpectrumOctahedral Hexarhenium ComplexBiophysicsBiomolecular Engineering
A new complex, [Re(6)S(8)Cl(5)ppy](3-) (ppy = 4-phenylpyridine), was synthesized and characterized. The complex showed red emission at 296 K in both the crystalline phase and CH(3)CN. The transient absorption spectrum of [Re(6)S(8)Cl(5)ppy](3-) revealed that the emissive excited state involved the {Re(6)(μ(3)-S)(8)} core-to-ligand charge-transfer character.
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