Inorganic Chemistry · 2013 · 85 citations · 54 references
Natural SciencesChemistryMaterials ScienceCrystal StructureMaterials ChemistryNanomaterialsCluster ChemistryCluster CompoundsCoordination ChemistryCrystal ChemistryCrystal EngineeringPorous MaterialsBuilding Block MethodologyGas AdsorptionLuminescent Metal-organic FrameworksMetal-organic Framework AdsorptionMetal-organic Framework SynthesisMetal-organic FrameworksPhotoluminescent MaterialsReversible Phase Transformations
A three-dimensional porous structure of [Zn7O2(bpdc)4(dmpp)2]·6DEF·10H2O (MAC-7, H2bpdc = 4,4'-biphenyldicarboxylic acid, Hdmpp = 3,5-dimethyl-4-(4'-pyridyl)pyrazole), built of 12-bridged carboxylate-pyrazolate shared Zn7O2 clusters, has been synthesized. Because of the presence of 12-bridged carboxylate-pyrazolate shared building block, MAC-7 is a double-linked pcu-type framework and shows reversible phase transformation. Photoluminescent property studies indicate that MAC-7 could sense nitrobenzene over toluene, p-xylene, and mesitylene by luminescent quenching.
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A short history of<i>SHELX</i>
George M. Sheldrick · Acta Crystallographica Section A Foundations of Crystallography · 2007 · 87.4K citations · Full text
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
Hailian Li, Mohamed Eddaoudi, M. O’Keeffe et al. · Nature · 1999 · 8.4K citations · Full text