Concepedia

Lewis and Brønsted Acid Induced (3 + 2)-Annulation of Donor–Acceptor Cyclopropanes to Alkynes: Indene Assembly

Eduard R. Rakhmankulov, Konstantin L. Ivanov, Alexey O. Chagarovskiy, Dmitry A. Skvortsov, Gennadij V. Latyshev, Igor V. Trushkov, Mikhail Ya. Melnikov

Organic Letters · 2015 · 50 citations · 40 references

DOI

Abstract

(3 + 2)-Annulation of donor-acceptor cyclopropanes to alkynes induced by both Lewis and Brønsted acids has been developed. The reaction provides a rapid approach to functionalized indenes displaying intense visible emission (λmax = 430 nm, Φ = 0.28-0.34).

References

40

A New Golden Age for Donor–Acceptor Cyclopropanes

Tobias F. Schneider, Johannes Kaschel, Daniel B. Werz · Angewandte Chemie International Edition · 2014 · 1.2K citations

[3+2] Cycloadditions of Aryl Cyclopropyl Ketones by Visible Light Photocatalysis

Zhan Lu, Mei‐Hua Shen, Tehshik P. Yoon · Journal of the American Chemical Society · 2011 · 317 citations · Full text

Recent advances in ring-forming reactions of donor–acceptor cyclopropanes

Mikhail Ya. Melnikov, Igor V. Trushkov · Mendeleev Communications · 2011 · 244 citations

Recent Applications of Cyclopropane-Based Strategies to Natural Product Synthesis

Yong Qin, Pei Tang · Synthesis · 2012 · 226 citations

, , +10

Stereospecific Formal [3+2] Dipolar Cycloaddition of Cyclopropanes with Nitrosoarenes: An Approach to Isoxazolidines

Shyamal Chakrabarty, Indranil Chatterjee, Birgit Wibbeling et al. · Angewandte Chemie International Edition · 2014 · 177 citations · Full text