A Large-Scale Synthesis of α-Olefins and α,ω-Dienes

George A. Kraus, Sean Riley

Synthesis · 2012 · 48 citations · 0 references

Concepts

Abstract

The decarbonylation of carboxylic acids or dicarboxylic acids in the presence of a palladium catalyst above 190 °C in the absence of a solvent constitutes a mild method for the large-scale synthesis of α-olefins and α,ω-dienes.