Synthesis · 2012 · 48 citations · 0 references
EngineeringAlkene MetathesisMild MethodOrganic ChemistryCatalysisSynthetic ChemistryChemistryPalladium CatalystAsymmetric CatalysisLarge-scale SynthesisBiomolecular Engineering
The decarbonylation of carboxylic acids or dicarboxylic acids in the presence of a palladium catalyst above 190 °C in the absence of a solvent constitutes a mild method for the large-scale synthesis of α-olefins and α,ω-dienes.