Concepedia

The Palladium-Catalyzed Intermolecular C–H Chalcogenation of Arenes

Renhua Qiu, V. Prakash Reddy, Takanori Iwasaki, Nobuaki Kambe

The Journal of Organic Chemistry · 2014 · 137 citations · 38 references

DOI

Concepts

Abstract

Palladium catalyzes the intermolecular chalcogenation of carbazole, 2-phenylpyridine, benzo[h]quinolone, and indole derivatives with disulfides and diselenides via selective C-H bond cleavage, providing a convenient route to thio and selenoethers.

References

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Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

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Beyond Directing Groups: Transition‐Metal‐Catalyzed CH Activation of Simple Arenes

Nadine Kuhl, Matthew N. Hopkinson, Joanna Wencel‐Delord et al. · Angewandte Chemie International Edition · 2012 · 1.6K citations

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