A Multifunctional Organic–Inorganic Hybrid Structure Based on Mn<sup>III</sup>–Porphyrin and Polyoxometalate as a Highly Effective Dye Scavenger and Heterogenous Catalyst

Chao Zou, Zhijuan Zhang, Xuan Xu, Qihan Gong, Jing Li, Chuan-De Wu

Journal of the American Chemical Society · 2011 · 421 citations · 52 references

Concepts

Abstract

A two-step synthesis strategy has led to a unique layered polyoxometalate-Mn(III)-metalloporphyrin-based hybrid material. The hybrid solid demonstrates remarkable capability for scavenging of dyes and for heterogeneous selective oxidation of alkylbenzenes with excellent product yields and 100% selectivity.

References

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