High Nuclearity in Azido/Oximate Chemistry: Ni<sub>14</sub> and Ni<sub>13</sub> Clusters with <i>S</i> = 6 and 9 Ground States

Jordi Esteban, Laura Alcázar, Maria Torres-Molina, Montserrat Monfort, Mercè Font‐Bardía, Albert Escuer

Inorganic Chemistry · 2012 · 37 citations · 16 references

Concepts

Abstract

In the present work, we report a family of Ni(14) and unprecedented Ni(13) clusters linked by end-on azido and oximato bridges. Ferrimagnetic response gives S = 6 and 9 ground states, resulting in the largest nuclearities and spins in nickel oximato chemistry.

References

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