Concepedia

Facile Catch and Release of Fullerenes Using a Photoresponsive Molecular Tube

Norifumi Kishi, Munetaka Akita, Motoshi Kamiya, Shigehiko Hayashi, Hsiu‐Fu Hsu, Michito Yoshizawa

Journal of the American Chemical Society · 2013 · 194 citations · 34 references

DOI

Concepts

Abstract

A novel M2L2 molecular tube capable of binding fullerene C60 was synthesized from bispyridine ligands with embedded anthracene panels and Ag(I) hinges. Unlike previous molecular cages and capsules, this open-ended tubular host can accommodate a single molecule of various C60 derivatives with large substituents. The fullerene guest can then be released by using the ideal, noninvasive external stimulus, light.

References

34

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