Inorganic Chemistry · 2012 · 247 citations · 36 references
Natural SciencesBiochemistryChemistryBiocatalysisBioorganic ChemistryCatalysisBioinorganic ChemistryHeme Redox ChemistryIron OxidesMetal OxidesMetal-ligand BondingRedox EnzymesBiomimetic CatalysisHeme-dependent CatalysisMetal-organic Framework CatalystsMetal-organic Framework Redox MaterialsMetal-organic FrameworksOrganic Solvent ExposurePorphyrin ComplexesPorphyrin Redox Chemistry
A porous metal-metalloporphyrin framework, MMPF-6, based upon an iron(III)-metalated porphyrin ligand and a secondary binding unit of a zirconium oxide cluster was constructed; MMPF-6 demonstrated interesting peroxidase activity comparable to that of the heme protein myoglobin as well as exhibited solvent adaptability of retaining the peroxidase activity in an organic solvent.
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Reticular synthesis and the design of new materials
Omar M. Yaghi, M. O’Keeffe, N.W. Ockwig et al. · Nature · 2003 · 9K citations
Natural Sciences, Materials Engineering, Materials Science +9