Characterization and Bonding of the Cation [Ge{N(C<sub>6</sub>H<sub>3</sub>-2,6-<i>i</i>-Pr<sub>2</sub>)CMe}<sub>2</sub>CH]<sup>+</sup>: Comparison with the Isoelectronic Ga{N(C<sub>6</sub>H<sub>3</sub>-2,6-<i>i</i>-Pr<sub>2</sub>)CMe}<sub>2</sub>CH - Concepedia

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Characterization and Bonding of the Cation [Ge{N(C<sub>6</sub>H<sub>3</sub>-2,6-<i>i</i>-Pr<sub>2</sub>)CMe}<sub>2</sub>CH]<sup>+</sup>: Comparison with the Isoelectronic Ga{N(C<sub>6</sub>H<sub>3</sub>-2,6-<i>i</i>-Pr<sub>2</sub>)CMe}<sub>2</sub>CH

113

Citations

18

References

2001

Year

Matthias Stender, A.D. Phillips, Philip P. Power

Inorganic Chemistry

Inorganic ChemistryEngineeringPhysicsBiochemistryNatural SciencesChemical BondHydrogen BondPhysical ChemistryIsoelectronic GaReaction IntermediateChemistryQuantum ChemistryMolecular ChemistryElectronic Structure

Abstract

Reaction of Ge(Cl)Dipp2nacnac (Dipp2nacnac = {N(C6H3-2,6-i-Pr2)C(Me)}2CH) with B(C6F5)3 in the presence of H2O affords the salt [Ge(Dipp2nacnac)][HO{B(C6F5)3}2] whose cation [Ge(Dipp2nacnac)]+ is isoelectronic to its neutral gallium analogue Ga(Dipp2nacnac).

References

	Year	Citations

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