Development of Abraham model correlations for enthalpies of solvation of organic solutes dissolved in 1,3-dioxolane

Abstract

Published excess enthalpy of mixing data has been assembled from the chemical literature for binary mixtures containing 1,3-dioxalane. The experimental data were converted into partial molar enthalpies of solution and enthalpies of solvation for solutes dissolved in 1,3-dioxolane using standard thermodynamic relationships. The compiled enthalpy of solvation data for 59 different organic solutes was used to derive mathematical correlations based on the Abraham solvation parameter model. The derived correlations describe the experimental enthalpy of solvation data in 1,3-dioxolane to within a standard deviation of 2.0 kJ mol−1.