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Synthesis of (.BETA.-N-Sulfonylaminoalkyl)phosphines and Their Use in Palladium-Mediated Asymmetric Synthesis.
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1995
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Enantioselective SynthesisEngineeringAsymmetric Palladium-catalyzed HydrosilylationPalladium-mediated Asymmetric SynthesisOrganic ChemistryOrganometallic CatalysisCatalysisChemistryPharmacologyAsymmetric CatalysisSynthetic ChemistryHeck-type HydroarylationBiomolecular Engineering
A series of (β-N-sulfonylaminoalkyl)phosphine ligands has been developed and employed for asymmetric palladium-catalyzed hydrosilylation and Heck-type hydroarylation, affording up to 72% ee and 90% yield.