CdSe–CdS Nanoheteroplatelets with Efficient Photoexcitation of Central CdSe Region through Epitaxially Grown CdS Wings

Abstract

We synthesized a new type of optically active semiconductor nanoheterostructure based on CdSe nanoplatelets with epitaxially grown CdS flat branches or wings. CdS branches work as efficient photonic antenna in the blue spectral region, enhancing the excitation of CdSe band edge emission. The formation of CdSe-CdS nanoheteroplatelets instead of CdSe/CdS core-shell nanoplatelets was achieved using short-chain Cd ethylhexanoate and sulfur in octadecene as precursors for CdS overgrowth in the presence of acetate salt.