Concepedia

Rhodium-Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with Alkenes: Efficient Synthesis of Benzoxaphosphole 1-Oxides

Taekyu Ryu, Jaeeun Kim, Young-Chul Park, Sanghyuck Kim, Phil Ho Lee

Organic Letters · 2013 · 76 citations · 64 references

DOI

Concepts

Abstract

Rhodium-catalyzed tandem oxidative alkenylation and an intramolecular oxy-Michael reaction were developed using arylphosphonic acid monoethyl esters and alkenes under aerobic conditions, which produced benzoxaphosphole 1-oxides in good to excellent yields.

References

64

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

Tetsuya Satoh, Masahiro Miura · Chemistry - A European Journal · 2010 · 1.7K citations

, , +11

Palladium-Catalyzed Methylation and Arylation of sp<sup>2</sup> and sp<sup>3</sup> C−H Bonds in Simple Carboxylic Acids

Ramesh Giri, Nathan Maugel, Jiao-Jie Li et al. · Journal of the American Chemical Society · 2007 · 770 citations

, , +10

Rhodium(III)-Catalyzed Isoquinolone Synthesis: The N−O Bond as a Handle for C−N Bond Formation and Catalyst Turnover

Nicolas Guimond, Christina Gouliaras, Keith Fagnou · Journal of the American Chemical Society · 2010 · 765 citations

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

Souvik Rakshit, Christoph Grohmann, Tatiana Besset et al. · Journal of the American Chemical Society · 2011 · 755 citations

, , +11

Ligand-Enabled Reactivity and Selectivity in a Synthetically Versatile Aryl C–H Olefination

Dong‐Hui Wang, Keary M. Engle, Bing‐Feng Shi et al. · Science · 2009 · 736 citations