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Selective Oxidation of Cp<sub>2</sub>MoS<sub>2</sub> and Cp<sub>2</sub>MoS<sub>4</sub> To Give Cp<sub>2</sub>MoS<sub>2</sub>O and Cp<sub>2</sub>MoS<sub>4</sub>O, Respectively: A Novel Thermally Induced Oxygen Migration Converting 1-Oxo-Cp<sub>2</sub>MoS<sub>4</sub>O to 2-Oxo-Cp<sub>2</sub>MoS<sub>4</sub>O
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Citations
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References
1999
Year
Selective OxidationInorganic ChemistryChemical EngineeringOxygen Reduction ReactionEngineeringOxidation ResistanceFinal 2-Oxo ProductSolvent PolarityThermal CatalysisFirst-order KineticsCatalysisRedox ChemistryChemistryReactive Oxygen SpeciesChemical KineticsDeoxygenationElectrochemistry
Oxidation of Cp2MoSx, where x = 2, 4, with m-chloroperbenzoic acid gave Cp2MoS2O and Cp2MoS4O, respectively. In Cp2MoS4O the oxygen is attached to the 2-sulfur atom of the S4 ligand; however, an intermediate was isolated and identified as the 1-oxo isomer. It thermally rearranges via first-order kinetics with rate dependence on solvent polarity to give the final 2-oxo product.
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