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Explanation for Stereoselectivity of the cis-Dihydroxylation of cis-3,5-disubstituted Cyclopentenes.
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1994
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EngineeringHeterocyclicBiochemistry5-Disubstituted CyclopentenesNatural SciencesCieplak EffectsOrganic ChemistryStereoselective SynthesisChemistryHeterocycle ChemistryEnantioselective SynthesisBiomolecular EngineeringCis-3,5-disubstituted Cyclopentenes
Stereoselectivity of the cis-dihydroxylation of cis-3, 5-disubstituted cyclopentenes has been found to depend on the conformation of cyclopenetenes and has been explained by both steric and Cieplak effects.