Exclusive Photodimerization Reactions of Chromone-2-carboxylic Esters Depending on Reaction Media

Abstract

The irradiation of chromone-2-carboxylic esters resulted in the stereo- and regioselective formation of C(2) chiral anti-HH dimers from the triplet excited state. On the contrary, photolysis in the solid-state gave anti-HT dimers exclusively controlled by molecular arrangement in the crystal.