Publication | Closed Access
1,7-Palladium Migration via C−H Activation, Followed by Intramolecular Amination: Regioselective Synthesis of Benzotriazoles
89
Citations
46
References
2011
Year
Cross-coupling ReactionHigh RegioselectivitiesEngineeringAlkene MetathesisExcellent YieldsIntramolecular AminationC−h ActivationOrganic ChemistryRegioselective SynthesisOrganometallic CatalysisCatalysisChemistryAsymmetric CatalysisBiomolecular Engineering1,7-Palladium Migration
A novel 1,7-palladium migration-cyclization-dealkylation sequence for the regioselective synthesis of benzotriazoles has been developed. These reactions proceed in excellent yields with high regioselectivities. The mechanism of the reaction has also been investigated.
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