Physical Review E · 2014 · 129 citations · 24 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsOptical MaterialsOpticsLiquid CrystalsMagnetic AnisotropyMagnetism In SolidsMagneto-optic MaterialsOptical Properties Of SolidsPhase TransitionsLattice PeriodicityMagneto-optic EffectsNematic Liquid CrystalsPeriodicityPhase Transition TemperatureStripe FormationStripe PatternsTwist-bend Nematic Phase
We present magneto-optic measurements on two materials that form the recently discovered twist-bend nematic (N_{tb}) phase. This intriguing state of matter represents a fluid phase that is orientationally anisotropic in three directions and also exhibits translational order with periodicity several times larger than the molecular size. N_{tb} materials may also spontaneously form a visible, macroscopic stripe texture. We show that the optical stripe texture can be persistently inhibited by a magnetic field, and a 25T external magnetic field depresses the N-N_{tb} phase transition temperature by almost 1{∘}C. We propose a quantitative mechanism to account for this shift and suggest a Helfrich-Hurault-type mechanism for the optical stripe formation.
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Nematic twist-bend phase with nanoscale modulation of molecular orientation
Volodymyr Borshch, Y.-K. Kim, Jie Xiang et al. · Nature Communications · 2013 · 658 citations · Full text
Natural Sciences, Chemistry, Physics +15