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Studies on the α-(1, 4)linked Polysaccharides of D-Glucuronic Acid and D-Glucose. VII. Synthesis of 4-O-(α-D-Glucopyranosyl)-D-Glucuronic Acid.
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1965
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BiosynthesisBioorganic ChemistryEngineeringBiochemistryNatural SciencesGlycobiologyAcid Hydrolysis RateOrganic ChemistryD-glucuronic AcidCrystalline StatePolysaccharide-D-glucuronic AcidChemistryCarbohydrate-protein InteractionBiomolecular EngineeringGlycosylation
Hepta-O-acetyl-4-O-(α-D-glucopyranosyl)-D-glucuronic acid (VII) was obtained in crystalline state by potassium permanganate oxidation of 1, 2, 3, 2', 3', 4', 6'-hapta-O-acetyl-D-maltose (VI), and by de-acetylation of VII, 4-O-(α-D-glucopyranosyl)-D-glucuronic acid (GU) was obtained. The acid hydrolysis rate of GU was also decribed.