Organometallics · 2011 · 47 citations · 43 references
Natural SciencesChemistryInorganic ChemistryOrganometallic ChemistrySolid-state ChemistryCoordination ChemistryInorganic SynthesisMetal-ligand BondingOrganometallic SynthesisTransition Metal ChemistryTransition Metal ComplexesMild Reaction ConditionsOrganogold ChemistryRedox-active Metal ComplexesRuthenium-catalyzed CouplingTransition Metal-catalyzed SynthesisTransition-metal-catalyzed Functionalization
The transmetalation of aryl, alkynyl, and alkyl groups from organogold compounds to iron complexes offers an efficient synthesis of organoiron complexes under very mild conditions. This method could be extended to ruthenium complexes.
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A. Stephen K. Hashmi, Graham J. Hutchings · Angewandte Chemie International Edition · 2006 · 3.4K citations