Physical Review E · 2013 · 32 citations · 47 references
Natural SciencesPhysicsColloid ScienceCondensed Matter PhysicsCrystal StructureColloid ChemistryColloid StabilityColloidal Self-assemblyColloidal StabilitySelf-assembled NanostructuresColloidal AggregationColloidal Crystal StructureColloidal CrystalsColloidal InteractionsColloidal NanoparticlesColloidal SolutionsColloidal SuperstructuresPacking Of Colloids
The structure of colloids with competing interactions which are confined in a harmonic external trap potential is analyzed numerically by energy minimization in two spatial dimensions. A wealth of different cluster structures is found to be stable including clusters with a fringed outer rim (reminiscent to an ornamental border), clusters perforated with voids, as well as clusters with a crystalline core and a disordered rim. All cluster structures occur in a two-dimensional parameter space. The structural ordering can therefore be efficiently tuned by changing few parameters only providing access to a controlled fabrication of colloidal clusters.
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Equilibrium cluster formation in concentrated protein solutions and colloids
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