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The First Molecule Incorporating [η<sup>5</sup>-NC<sub>4</sub>H<sub>4</sub>]<sup>-</sup> and an Organic C−NC<sub>4</sub>H<sub>4</sub> Group. Synthesis of [Co(7-C<sub>4</sub>H<sub>4</sub>N(CH<sub>2</sub>)<sub>3</sub>-8-R-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>9</sub>)(η<sup>5</sup>-NC<sub>4</sub>H<sub>4</sub>)] (R = CH<sub>3</sub>, C<sub>6</sub>H<sub>5</sub>)
22
Citations
20
References
1997
Year
Inorganic ChemistryOrganic C−nc4h4 GroupEngineeringOrganic ChemistryFirst MoleculeOrganometallic CatalysisChemistrySynthetic ChemistryBiomolecular Engineering
The synthesis of [Co(7-C4H4N(CH2)3-8-R-7,8-C2B9H9)(η5-NC4H4)] (R = CH3, C6H5), the first molecule reported incorporating [η5-NC4H4]- and an organic C−NC4H4 group, is described. The molecular structure of the compound for R = CH3 is indicated in the diagram.
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