Vertically Aligned Arrays of BaTiO₃ Nanowires

Abstract

Barium titanate (BaTiO3) nanowires have gained considerable research interest due to their lead-free composition and strong energy conversion efficiency. However, most research has focused on free-standing BaTiO3 nanowires, which are hard to apply for sensing and energy harvesting. Here, a novel method for the growth of vertically aligned BaTiO3 nanowire arrays on a conductive substrate is developed, and their electromechanical coupling behavior is directly evaluated to yield the strain coupling coefficient. The preparation of vertically aligned BaTiO3 nanowire arrays is based on a two-step hydrothermal reaction by first growing oriented rutile TiO2 nanowire arrays and then converting them to BaTiO3 while simultaneously retaining their morphology. A refined piezoelectric force microscopy (PFM) testing method is applied to demonstrate the piezoelectric behavior of BaTiO3 nanowires in the longitude direction. The piezoelectric response (d33 = 43 ± 2 pm/V) of the BaTiO3 nanowires is measured to demonstrate their potential application in sensors, energy harvesting, and micro-electromechanical systems.