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Suillin, ein charakteristischer Inhaltsstoff von Röhrlingen der Gattung Suillus (Boletales) / Suillin, a Characteristic M etabolite from Boletes of the Genus Suillus (Boletales)
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1986
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BiologyBiosynthesisBioorganic ChemistryEngineeringNatural SciencesGenus SuillusSeveral Suillus SpeciesOrganic ChemistryCharacteristic M EtaboliteCyclic Carbonate 2ChemistryAbstract Fruiting Bodies
Abstract Fruiting bodies of several Suillus species contain a colourless compound, suillin, which is concentrated in the cuticle of the pileus. Its structure has been established as 4-acetoxy-3-geranyl-geranyl-1,2 -dihydroxybenzene (1) by spectroscopic evidence, conversion into a cyclic carbonate 2 and synthesis of its deacetyl derivative 3.