Construction of Polyoxometalate-Based Inorganic–Organic Compounds Using Silver(I) Double Helicates as Secondary Building Blocks

Abstract

Two polyoxometalate-based silver(I) compounds including a three-dimensional porous crystalline array and a double-helicate bisupporting cluster were achieved using metal-organic helicates and Keggin [PMo(12)O(40)](3-) as secondary building blocks.